The concentrations of the solute species in the 0.15 M solution of ascorbic acid are approximately:
[H⁺] ≈ 3.464 x 10⁻³ M
[HC₆H₆O₆⁻] ≈ 0.1465 M
[C₆H₆O₆²⁻] ≈ 3.464 x 10⁻³ M
The pH of the solution is approximately 2.46.
To determine the concentrations of all solute species and the pH of the solution, we need to consider the dissociation of ascorbic acid (vitamin C) and its corresponding equilibrium reactions.
The dissociation of ascorbic acid can be represented as follows:
HC₆H₆O₆ ⇌ H⁺ + C₆H₆O₆⁻ (Equation 1)
The equilibrium constant (Kₐ₁) for this reaction is given as 8.0 x 10⁻⁵.
Since the problem states that we have a 0.15 M solution of ascorbic acid, initially, the concentration of HC₆H₆O₆ is 0.15 M. We can assume that the concentration of H⁺ and C₆H₆O₆⁻ is initially zero.
Let's define the changes in concentration for H⁺ and C₆H₆O₆⁻ as x. Then, the changes in concentration for HC₆H₆O₆ would be -x and -x, respectively.
After equilibrium is reached, we can set up an ICE (Initial, Change, Equilibrium) table:
Species | HC₆H₆O₆ | H⁺ | C₆H₆O₆⁻
Initial | 0.15 | 0 | 0
Change | -x | +x | +x
Equilibrium | 0.15-x | x | x
Using the equilibrium constant expression for Equation 1:
Kₐ₁ = [H⁺][C₆H₆O₆⁻] / [HC₆H₆O₆]
Plugging in the values from the equilibrium concentrations:
8.0 x 10⁻⁵ = x(x) / (0.15 - x)
Since Kₐ₁ is small (compared to the initial concentration of ascorbic acid), we can approximate 0.15 - x as 0.15:
8.0 x 10⁻⁵ ≈ x * x / 0.15
Rearranging the equation:
x² ≈ 8.0 x 10⁻⁵ * 0.15
x² ≈ 1.2 x 10⁻⁵
Taking the square root of both sides:
x ≈ √(1.2 x 10⁻⁵)
x ≈ 3.464 x 10⁻³
Now we can calculate the concentrations of the solute species:
[H⁺] = x ≈ 3.464 x 10⁻³ M
[HC₆H₆O₆⁻] = 0.15 - x ≈ 0.15 - 3.464 x 10⁻³ ≈ 0.1465 M
[C₆H₆O₆²⁻] = x ≈ 3.464 x 10⁻³ M
To calculate the pH of the solution, we can use the equation:
pH = -log[H⁺]
pH ≈ -log(3.464 x 10⁻³)
pH ≈ -(-2.46)
pH ≈ 2.46
The pH of the solution is approximately 2.46. This indicates that the solution is acidic since the pH is less than 7.
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Rank the following compounds in the order of increasing acidity (from least acidic to the most acidic). Explain your answer using the appropriate resonance structures.
1. acetic acid
2. ethanol
3. phenol
4. acetone
The following compounds in the order of increasing acidity (from least acidic to the most acidic) are: ethanol, acetone, acetic acid, phenol.
The acidity of a compound can be measured by its ability to donate a proton. When the proton donates, it forms a negatively charged ion that stabilizes through resonance. The higher the stability of the negative ion, the stronger the acid.
Ethanol: Ethanol is less acidic compared to the other compounds given. The oxygen atom in ethanol is bonded to carbon, and hydrogen is bonded to another carbon atom. The carbon-oxygen bond's electronegativity difference results in a polar bond. There is no possibility of resonance stabilization because the negative charge resides on the oxygen atom. Therefore, ethanol is less acidic.
Acetone: Acetone is slightly acidic, and it has a higher acidity than ethanol. Acetone is a ketone that contains two carbonyl groups. The carbonyl group is more polar than the carbon-oxygen bond in ethanol. In the presence of a strong base, the alpha-hydrogen atom of the carbonyl group can undergo deprotonation. However, there is no possibility of resonance stabilization, resulting in a slightly acidic nature.
Acetic Acid: Acetic acid is a carboxylic acid that contains a polar carbon-oxygen bond. The electron-withdrawing effect of the adjacent carbonyl group increases the polarity of the carbon-oxygen bond. The adjacent carbonyl group also allows for resonance stabilization of the negative charge formed after deprotonation.Therefore, acetic acid is more acidic than acetone and ethanol.
Phenol: Phenol is the most acidic among the given compounds. The negative charge formed after deprotonation stabilizes through resonance. The conjugate base formed has resonance structures that result from electron delocalization throughout the benzene ring, leading to higher stability. Therefore, phenol is the most acidic.
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mr. t has a gold chain with a mass of 100 grams. the density of gold is 19.3 g/cm3. in liters, what is the volume of mr. t’s gold chain?
To determine the volume of Mr. T's gold chain in liters, we need to use the density of gold and the mass of the chain. The density of gold is given as 19.3 g/cm3, and the mass of the chain is 100 grams. By dividing the mass by the density, we can calculate the volume of the gold chain. To convert the volume from cubic centimeters (cm3) to liters, we divide by 1000.
The density of a substance is defined as its mass per unit volume. In this case, the density of gold is given as 19.3 g/cm3. Mr. T's gold chain has a mass of 100 grams.
To calculate the volume, we use the formula:
Volume = Mass / Density
Substituting the given values, we have:
Volume = 100 g / 19.3 g/cm3
Calculating the result, we find:
Volume = 5.18 cm3
To convert the volume from cubic centimeters (cm3) to liters, we divide by 1000:
Volume = 5.18 cm3 / 1000 = 0.00518 liters
Therefore, the volume of Mr. T's gold chain is approximately 0.00518 liters.
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Give the ground-state electron configuration for each of the following elements:
(a) Oxygen
(b) Nitrogen
(c) Sulfur
The ground-state electron configuration for oxygen is[tex]\(1s^2 2s^2 2p^4\)[/tex], nitrogen is [tex]\(1s^2 2s^2 2p^3\),[/tex] and sulfur is [tex]\(1s^2 2s^2 2p^6 3s^2 3p^4\).[/tex]
The ground-state electron configuration describes how electrons are distributed in the energy levels and sublevels of an atom in its lowest energy state. Each electron occupies the lowest available energy level and sublevel before filling higher ones.
For oxygen [tex](\(O\))[/tex], it has 8 electrons. The first two electrons occupy the 1s sublevel, the next two electrons occupy the 2s sublevel, and the remaining four electrons occupy the 2p sublevel, where [tex]\(p\)[/tex] has three orbitals and can hold a total of six electrons. Therefore, the electron configuration of oxygen is [tex]\(1s^2 2s^2 2p^4\)[/tex].
For nitrogen [tex](\(N\))[/tex], it has 7 electrons. Similar to oxygen, the first two electrons occupy the 1s sublevel, the next two electrons occupy the 2s sublevel, and the remaining three electrons occupy the 2p sublevel. The 2p sublevel has three orbitals, and nitrogen fills one of them with two electrons and another one with a single electron. Thus, the electron configuration of nitrogen is [tex]\(1s^2 2s^2 2p^3\)[/tex].
For sulfur [tex](\(S\))[/tex], it has 16 electrons. Following the same pattern as oxygen and nitrogen, the first two electrons occupy the 1s sublevel, the next two electrons occupy the 2s sublevel, and the next six electrons occupy the 2p sublevel. After that, the remaining eight electrons fill the 3s and 3p sublevels. The 3p sublevel has three orbitals and can hold a total of six electrons, so sulfur fills all three orbitals with six electrons. Therefore, the electron configuration of sulfur is [tex]\(1s^2 2s^2 2p^6 3s^2 3p^4\)[/tex].
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if the concentration of a reactant is doubled and the reaction rate is unchanged, what must be the order of the reaction?
If the concentration of a reactant is doubled and the reaction rate is unchanged, the reaction must be a zero-order reaction.
The order of a reaction represents how the rate of the reaction is affected by the concentration of the reactants. It can be determined by comparing the changes in the reaction rate with changes in the concentration of the reactants.
In a zero-order reaction, the reaction rate is independent of the concentration of the reactants. This means that doubling the concentration of a reactant will not have any effect on the reaction rate. In contrast, for a first-order reaction, doubling the concentration of a reactant would result in a doubling of the reaction rate. Similarly, for a second-order reaction, doubling the concentration of a reactant would lead to a fourfold increase in the reaction rate.
Since the given scenario states that the reaction rate remains unchanged despite doubling the concentration of the reactant, it implies that the reaction is a zero-order reaction.
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5. what volume of 5.00 × 10−3 m hno3 is needed to titrate 100.00 ml of 5.00 × 10−3 m ca(oh)2 to the equivalence point? a) 12.5 ml b) 200. ml c) 50.0 ml d) 100. ml
The volume of the acid that is requirted from the calculation is 200 mL
What is neutralization reaction?Neutralization refers to a chemical reaction that occurs between an acid and a base, resulting in the formation of a salt and water. It is a process in which the acidic and basic properties of the reactants are neutralized, leading to the formation of a neutral or near-neutral solution.
We have the reaction as;
2HNO3 + Ca(OH)2 -----> Ca(NO3)2 + 2H2O
Number of moles of the base = 100/1000 * 0.005
= 0.0005 moles
If 2 moles of acid reacts with 1 mole of the base
x moles of the acid reacts with 0.0005 moles of base
x = 0.001 moles
Now;
n = CV
V = n/C
V = 0.001/0.005
V = 0.2 L or 200 mL
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Helium is compressed isentropically from 1 atmosphere and 5°C to a pressure of 8
atmospheres. The ratio of specific heats for helium is 5/3. What is the final temperature of the
helium?
(A) 290°C
(B) 340°C
(C) 370°C
(D) 650°C
370°C is the final temperature of the helium if Helium is compressed isentropically from 1 atmosphere and 5°C to a pressure of 8 atmospheres
Define temperature
The concept of temperature is used to convey quantitatively how hot and cold something is. Using a thermometer, one can gauge temperature.
Thermometers are calibrated using different temperature scales that traditionally relied on different reference points and thermometric materials for definition. The most popular scales are the Kelvin scale (K), which is mostly used for scientific reasons, the Fahrenheit scale (°F), and the Celsius scale, with the unit symbol °C (formerly known as centigrade). One of the seven base units in the International System of Units (SI) is the kelvin.
T_{2}/T_{1} = (P_{1}/P_{2}) ^ ((1 - k)/2)
(1 - k)/k = (1 - 8/3)/(8/3) = (3 - 8)/8 = - 0.6
T_{2} = T_{1} * (P_{1}/P_{2}) ^ ((1 + k)/2) = (5' * C + 273) * ((1atm)/(8atm)) ^ - 0.6
T_{2} = 638.7K ≈ 370°C
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All of the following compounds would produce an electrolyte solution when dissolved in water except:
A) Glucose B) Magnesium sulfate C) Ammonium chloride D) Potassium iodide
The compound that would not produce an electrolyte solution when dissolved in water among the given options is glucose (option A). Magnesium sulfate (option B), ammonium chloride (option C), and potassium iodide (option D) are all ionic compounds that dissociate into ions when dissolved in water, making them electrolytes. In contrast, glucose is a covalent compound that does not dissociate into ions in water, resulting in a non-electrolyte solution.
An electrolyte is a substance that, when dissolved in water or another solvent, dissociates into ions and conducts electricity. Ionic compounds, which are formed by the transfer of electrons between atoms, are typically strong electrolytes. When they dissolve in water, the positive and negative ions separate and are free to move, allowing the solution to conduct electricity.
Among the given options, glucose (option A) is a covalent compound consisting of carbon, hydrogen, and oxygen atoms. Covalent compounds share electrons rather than transferring them, and therefore, they do not dissociate into ions when dissolved in water. As a result, glucose does not produce an electrolyte solution.
On the other hand, magnesium sulfate (option B), ammonium chloride (option C), and potassium iodide (option D) are all ionic compounds. Magnesium sulfate dissociates into magnesium ions (Mg2+) and sulfate ions (SO42-), ammonium chloride dissociates into ammonium ions (NH4+) and chloride ions (Cl-), and potassium iodide dissociates into potassium ions (K+) and iodide ions (I-). When these compounds dissolve in water, the ions separate and can conduct electricity, making them electrolytes.
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Gaseous ethane (CH3CH3) reacts with gaseous oxygen gas (O2) to produce gaseous carbon dioxide (CO2) and gaseous water (H2O). If 0.179 of water is produced from the reaction of 0.90g of ethane and 1.0g of oxygen gas, calculate the percent yield of water. Round your answer to 2 significant figures.
The percent yield of water in the reaction is 37%. 37% of the maximum possible yield of water was obtained based on the given amounts of ethane and oxygen gas.
To calculate the percent yield of water, we need to compare the actual yield of water (given as 0.179 g) with the theoretical yield of water, which can be calculated based on the stoichiometry of the reaction.
The balanced equation for the reaction is:
C2H6(g) + O2(g) -> CO2(g) + H2O(g)
From the equation, we can see that the molar ratio between ethane and water is 1:3. This means that for every 1 mole of ethane, 3 moles of water are produced.
Mass of ethane (C2H6) = 0.90 g
Mass of oxygen gas (O2) = 1.0 g
Mass of water (H2O) = 0.179 g
First, we need to calculate the moles of ethane and oxygen gas used in the reaction:
Moles of ethane = Mass of ethane / molar mass of ethane
Moles of oxygen gas = Mass of oxygen gas / molar mass of oxygen gas
Next, we calculate the limiting reagent, which is the reactant that is completely consumed and determines the maximum amount of product that can be formed. The limiting reagent is the one that produces the smaller amount of product based on the stoichiometry of the reaction.
To determine the limiting reagent, we compare the moles of each reactant to the stoichiometric ratio in the balanced equation. The reactant that produces fewer moles of water is the limiting reagent.
Once we know the limiting reagent, we can calculate the theoretical yield of water based on the stoichiometric ratio.
Finally, we can calculate the percent yield using the formula:
Percent yield = (Actual yield / Theoretical yield) * 100
The percent yield of water in the reaction is 37%. This means that 37% of the maximum possible yield of water was obtained based on the given amounts of ethane and oxygen gas.
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Write a complete and balanced equation for the reaction of solid magnesium and silver nitrate solution.
The balanced equation for the reaction of solid magnesium and silver nitrate solution is: `Mg(s) + 2AgNO₃(aq) → Mg(NO₃)₂(aq) + 2Ag(s)`.
This equation shows that one atom of magnesium reacts with two molecules of silver nitrate to produce one molecule of magnesium nitrate and two atoms of solid silver. The coefficients in the equation are balanced to ensure that the same number of atoms of each element are present on both sides of the equation.
In this reaction, magnesium is a more reactive metal than silver, so it displaces the silver from the silver nitrate solution. This is an example of a single replacement reaction, in which one element replaces another in a compound.
Overall, this reaction is exothermic, meaning that it releases heat energy as it occurs. The balanced equation allows us to predict the amount of each reactant and product that will be present in the reaction, as well as the energy changes that will occur.
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Predict which of the following two compounds will undergo an E2 reaction more rapidly:
O The cis isomer is faster because the Cl predominantly occupies an equatorial position.
O The cis isomer is faster because the Cl predominantly occupies an axial position.
O The trans isomer is faster because the CI predominantly occupies an axial position.
O The trans isomer is faster because the CI predominantly occupies an equatorial position.
The correct answer is: The trans isomer is faster because the CI predominantly occupies an axial position.
In an E2 (elimination) reaction, the rate of reaction is influenced by the orientation of the reacting groups. The reaction occurs through a concerted mechanism, where the leaving group and the hydrogen being removed are anti-coplanar to each other.
In the case of the cis and trans isomers, the arrangement of substituents around a double bond determines the accessibility of the hydrogen and the leaving group in an E2 reaction.
The trans isomer has the hydrogen and the leaving group (CI) in an anti-coplanar arrangement, which is favorable for an E2 reaction. This arrangement allows for efficient overlap of the orbitals involved in the bond formation and breaking during the reaction. Therefore, the trans isomer is more likely to undergo an E2 reaction more rapidly.
Conversely, the cis isomer has the hydrogen and the leaving group in a syn-coplanar arrangement, which is less favorable for an E2 reaction. The steric hindrance between the substituents can hinder the proper alignment of orbitals required for the reaction to occur efficiently.
Hence, the trans isomer is faster because the CI predominantly occupies an axial position, providing a better arrangement for an E2 reaction.
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The complete question is:
Predict which of the following two compounds will undergo an E2 reaction more rapidly:
The cis isomer is faster because the Cl predominantly occupies an equatorial position.
The cis isomer is faster because the Cl predominantly occupies an axial position.
The trans isomer is faster because the Cl predominantly occupies an axial position.
The trans isomer is faster because the Cl predominantly occupies an equatorial position.
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How much energy does the water in this experiment absorb according to the calorimeter data?
The heat energy absorbed by the water in the experiment according to the calorimeter data is 10450 J
How do i determine the heat energy absorbed by the water?From the question give above, the following data were obtained:
Mass of water (M) = 100.0 gSpecific heat capacity of water (C) = 4.18 J/gºC Initial temperature of water (T₁) = 21.2 °CFinal temperature of water (T₂) = 46.2 °CChange in temperature (ΔT) = 46.2 - 21.2 = 25 °C Heat absorbed by water (Q) =?From calorimetry, we understood that heat absorbed is given by the following formula
Q = MCΔT
Inputting the given parameters, we can obtain the heat absorbed by the water as follow:
Q = 100 × 4.18 × 25
Q = 10450 J
Thus, we can conclude that the heat energy absorbed by the water is 10450 J
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if the half-life of carbon-14 is 5730 years, how many years will it take for a 100 g sample of carbon to decay to 6.25 g?
In this case, it will take approximately 22920 years for a 100 g sample of carbon to decay to 6.25 g.
The time it takes for a 100 g sample of carbon to decay to 6.25 g can be determined using the concept of half-life. Carbon-14 has a half-life of 5730 years, meaning that after every 5730 years, half of the original amount of carbon-14 decays. To calculate the time required, we can use the formula for exponential decay and solve for the unknown time. The half-life of carbon-14 is 5730 years, which means that after 5730 years, half of the original amount of carbon-14 will have decayed. Using this information, we can set up an exponential decay equation to solve for the time required to decay from 100 g to 6.25 g.
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Rank from highest to lowest melting point. To rank items as equivalent,
o overlap them.
o sodium chloride
o graphite
o solid ammonia
To rank from highest to lowest melting point, the following order should be followed:
Sodium chloride > Solid ammonia > Graphite.
Explanation:
Sodium chloride: It has a very high melting point of 1474°F (801°C). The ionic bond between the metal and the nonmetal is very strong, requiring a lot of heat to break. Sodium chloride is formed when a sodium atom transfers an electron to a chlorine atom.
Graphite:It has a melting point of about 3652°F (2027°C). Graphite is a nonmetal made up of carbon atoms that are arranged in a hexagonal lattice.
Solid ammonia: It has a melting point of -107.9°C. As ammonia is cooled, it eventually freezes, and the freezing point of ammonia is -107.9°C. It is important to note that this occurs at atmospheric pressure.
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he kb for a weak base is 2.2 x 10-9. what will be the ka for its conjugate acid at 25 oc? group of answer choices
8.2 x 10-3 5.6 x 10-7 4.5 x 10-6 2.2 x 10-9 1.8 x 10-8
The Ka for the conjugate acid of the weak base is approximately 4.55 x 10⁻⁶. Option C is correct.
To calculate the Ka for the conjugate acid of a weak base, we can use the relationship between the Ka and Kb values. The Kw (ionic product of water) can also be utilized.
Kw = Ka × Kb
At 25 °C, the value of Kw is approximately 1.0 x 10⁻¹⁴.
Given that the Kb of the weak base is 2.2 x 10⁻⁹, we can substitute these values into the equation;
1.0 x 10⁻¹⁴ = Ka × (2.2 x 10⁻⁹)
Simplifying the equation;
Ka = (1.0 x 10⁻¹⁴) / (2.2 x 10⁻⁹)
Performing the division;
Ka ≈ 4.55 x 10⁻⁶
Therefore, the Ka for the conjugate acid of the weak base will be 4.55 x 10⁻⁶.
Hence, C. is the correct option.
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--The given question is incomplete, the complete question is
"The kb for a weak base is 2.2 x 10-9. what will be the ka for its conjugate acid at 25 oc? group of answer choices A) 8.2 x 10⁻³ B) 5.6 x 10⁻⁷ C) 4.55 x 10⁻⁶ D) 2.2 x 10⁻⁹ E) 1.8 x 10⁻⁸."--
Seperate this redox reaction into its component half reactions( use the symbol e- for an electron)
3O2 + 4Cr ---> 2Cr2O3
Oxidation half reaction:
Reduction half reaction:
For the given redox reaction- [tex]3O_2 + 4Cr \rightarrow 2Cr_2O_3[/tex],
Oxidation half reaction is: [tex]Cr \rightarrow Cr^{3+} + 3e^{-}[/tex]
Reduction half reaction is: [tex]O_{2} + 4e^{-} \rightarrow 2O^{2-}[/tex]
Redox reactions are those that involve simultaneous oxidation and reduction processes.
The word refers to a reduction reaction in which an atom obtains electrons. The atom's oxidation number falls during this reaction.
An oxidation reaction is described as the loss of an atom's electrons. During this reaction, the atom's oxidation number rises.
We must determine the species that experience oxidation and reduction in order to divide the redox reaction into its two component half processes. In the following response:
We must determine the species that experience oxidation and reduction in order to divide the redox reaction into its component half processes. In the given reaction: [tex]3O_2 + 4Cr \rightarrow 2Cr_2O_3[/tex]
The chromium (Cr) atoms are being oxidized because their oxidation state increases from 0 to +3 in chromium(III) oxide.
On the other hand, the molecular oxygen is being reduced because its oxidation state decreases from 0 to -2 in the oxide ions.
Thus, oxidation half reaction becomes- [tex]Cr \rightarrow Cr^{3+} + 3e^{-}[/tex]
While, the reduction half reaction becomes- [tex]O_{2} + 4e^{-} \rightarrow 2O^{2-}[/tex]
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Calculate the number of moles in the following samples.
(a) 2.2 g K2SO4
(b) 6.4 g C8H12N4
(c) 7.13 g Fe(C5H5)2
The number of moles in the given samples are:(a) 0.0126 mol(b) 0.0389 mol(c) 0.0383 mol.
The formula for the number of moles can be given by the following expression:n = m/M where m is the mass of the sample, and M is the molar mass of the substance. We need to calculate the number of moles of each of the following samples:(a) 2.2 g K2SO4The molar mass of K2SO4 is 174.26 g/mol.Number of moles of K2SO4 = 2.2 g / 174.26 g/mol= 0.0126 mol(b) 6.4 g C8H12N4The molar mass of C8H12N4 is 164.21 g/mol.Number of moles of C8H12N4 = 6.4 g / 164.21 g/mol= 0.0389 mol(c) 7.13 g Fe(C5H5)2The molar mass of Fe(C5H5)2 is 186.03 g/mol.Number of moles of Fe(C5H5)2 = 7.13 g / 186.03 g/mol= 0.0383 molTherefore, the number of moles in the given samples are:(a) 0.0126 mol(b) 0.0389 mol(c) 0.0383 mol.
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Consider a Hydrogen atom with the electron in the n = 9 shell. What is the energy of this system? (The magnitude of the ground state energy of the Hydrogen atom is 13.6 eV.)
Tries 0/20 How many subshells are in this shell?
Tries 0/20 How many electron orbits are in this main shell?
Tries 0/20 How many electrons would fit in this main shell?
Tries 0/20
The energy of the system is -0.17 eV. There are 9 subshells in this shell. There are 9 electron orbits in the main shell. The maximum number of electrons that would fit in the n = 9 shell is 162.
The energy of the Hydrogen atom with the electron in the n = 9 shell can be calculated using the formula:
[tex]$$E_n = -\frac{13.6}{n^2} \ eV$$[/tex]
where n is the principal quantum number. So, substituting n = 9:
[tex]$$E_9 = -\frac{13.6}{9^2} \ eV = -0.17 \ eV$$[/tex]
Therefore, the energy of the Hydrogen atom with the electron in the n = 9 shell is -0.17 eV.
In the n = 9 shell, there are 9 subshells. This is because the maximum number of subshells in a shell is equal to the value of the principal quantum number.
In the n = 9 shell, there are 9 electron orbits. This is because the maximum number of electron orbits in a shell is equal to the value of the principal quantum number.
In the n = 9 shell, the maximum number of electrons that can fit is given by the formula:
[tex]$$2n^2 = 2(9)^2 = 162$$[/tex]
Therefore, the maximum number of electrons that would fit in the n = 9 shell is 162.
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Would the pH at the equivalence point be acidic, basic, or neutral for each given titration?
CH3COOH with Sr(OH)2
Choose...BasicAcidicNeutral
HCl with NH3
Choose...BasicAcidicNeutral
HClO4 with Ba(OH)2
Choose...BasicAcidicNeutral
The pH at the equivalence point of the titration between CH₃COOH and Sr(OH)₂ is basic, the pH at the equivalence point of the titration between HCl and NH₃ is acidic, and the pH at the equivalence point of the titration between HClO₄ and Ba(OH)₂ is neutral.
For the titration of CH₃COOH with Sr(OH)₂:
The reaction between CH₃COOH (acetic acid) and Sr(OH)₂ (strontium hydroxide) produces a salt, Sr(CH₃COO)₂, and water. The salt Sr(CH₃COO)₂ is a weak base.
At the equivalence point, all of the acetic acids reacted with strontium hydroxide, resulting in the formation of the salt. The salt Sr(CH₃COO)₂ will hydrolyze in water, producing hydroxide ions (OH⁻).
Therefore, at the equivalence point, the pH will be basic.
For the titration of HCl with NH₃:
The reaction between HCl (hydrochloric acid) and NH₃ (ammonia) produces ammonium chloride (NH₄Cl).
At the equivalence point, all of the hydrochloric acids have reacted with ammonia, resulting in the formation of ammonium chloride. Ammonium chloride is a salt.
The salt NH₄Cl will dissociate in water to produce ammonium ions (NH₄⁺) and chloride ions (Cl⁻). The presence of the ammonium ions will make the solution acidic.
Therefore, at the equivalence point, the pH will be acidic.
For the titration of HClO₄ with Ba(OH)₂:
The reaction between HClO₄ (perchloric acid) and Ba(OH)₂ (barium hydroxide) produces barium perchlorate (Ba(ClO₄)₂) and water.
At the equivalence point, all of the perchloric acids reacted with barium hydroxide, resulting in the formation of barium perchlorate. Barium perchlorate is a salt.
The salt Ba(ClO₄)₂ will dissociate in water to produce barium ions (Ba²⁺) and perchlorate ions (ClO₄⁻). The presence of the barium ions will not significantly affect the pH of the solution.
Therefore, at the equivalence point, the pH will be neutral.
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37.4 g iron (II) chloride in solution was mixed with 42.3 g potassium permanganate in the
presence of acid. The following reaction occurred:
FeCl2 + KMnO4 + HCl → FeCl3 + MnCl2 + KCl + H2O
a1. What mass (g) of iron (III) chloride was produced?
a2. How many moles of HCl were required?
a3. What mass (g) of the excess reactant was not used?
Answer: See below
Explanation:
a1. To determine the mass of iron (III) chloride produced, we need to first determine the limiting reagent. Using the mole ratio method [2], we can compare the number of moles of FeCl2 and KMnO4 to find the limiting reagent. The balanced equation shows that 1 mole of FeCl2 reacts with 1 mole of KMnO4.
Moles of FeCl2 = 37.4 g ÷ 126.75 g/mol = 0.295 moles
Moles of KMnO4 = 42.3 g ÷ 158.03 g/mol = 0.267 moles
Since KMnO4 produces fewer moles of product, it is the limiting reagent. Therefore, we need to use the mole ratio of KMnO4 to determine the moles of FeCl3 produced.
Moles of FeCl3 = 0.267 moles KMnO4 × (1 mole FeCl3 ÷ 1 mole KMnO4) = 0.267 moles
Now, we can determine the mass of FeCl3 produced using the mass of the product and its molar mass [1].
Mass of FeCl3 = 0.267 moles × 162.2 g/mol = 43.2 g
Therefore, 43.2 g of iron (III) chloride was produced.
a2. From the balanced equation, we can see that 2 moles of HCl are required to react with 1 mole of FeCl2. Therefore, we can use the mole ratio of FeCl2 and HCl to determine the moles of HCl required [2].
Moles of HCl = 0.295 moles FeCl2 × (2 moles HCl ÷ 1 mole FeCl2) = 0.59 moles
Therefore, 0.59 moles of HCl were required.
a3. To determine the mass of the excess reactant, we need to first determine the amount of the limiting reactant used. From the previous calculations, we know that 0.267 moles of KMnO4 reacted, so we can subtract this from the total moles of KMnO4 to find the excess [3].
Moles of excess KMnO4 = 0.267 moles total KMnO4 - 0.267 moles reacted = 0.267 moles
Now, we can determine the mass of the excess KMnO4 using its molar mass [1].
Mass of excess KMnO4 = 0.267 moles × 158.03 g/mol = 42.2 g
Therefore, 42.2 g of the excess reactant was not used.
a1. The mass of iron (III) chloride produced can be calculated using stoichiometry.
a2. The moles of HCl required can be determined from the balanced equation and stoichiometry.
a3. The mass of the excess reactant can be calculated by subtracting the mass of the reactant consumed from the initial mass.
a1. To determine the mass of iron (III) chloride produced, we need to compare the stoichiometry of the balanced equation with the given amounts of reactants. From the balanced equation, we can see that the molar ratio between FeCl_{2} andFeCl_{3}is 1:1. Therefore, the mass of iron (III) chloride produced is also 37.4 g.
a2. Using the balanced equation, we can determine the stoichiometric relationship between HCl and FeCl_{2}. The equation shows a 1:1 molar ratio between HCl andFeCl_{2}. Therefore, the moles of HCl required are equal to the moles of FeCl_{2}, which can be calculated by dividing the mass ofFeCl_{2} (37.4 g) by its molar mass.
a3. To find the mass of the excess reactant, we need to identify the limiting reactant first. The limiting reactant is the one that is completely consumed and determines the amount of product formed. To determine the limiting reactant, we compare the stoichiometry of the balanced equation with the given amounts of reactants. From the balanced equation, we can see that the molar ratio between[tex]FeCl_{2}[/tex]and [tex]KMnO{4}[/tex] is 1:1. By calculating the moles of each reactant using their respective masses and molar masses, we can determine which reactant is in excess. The mass of the excess reactant can be calculated by subtracting the mass of the reactant consumed from the initial mass.
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When 2.16 g of H2 reacts with excess O2 by the following equation, 258 kJ of heat are released.
What is the change of enthalpy associated with the reaction of 1 mol of hydrogen gas?
2H2 + O2 ⟶ 2H2O
*Round your answer to the nearest whole number.
*Include a negative sign if appropriate.
The change of enthalpy associated with the reaction of 1 mol of hydrogen gas is -241 kJ. This is calculated by dividing the heat released when 2.16 g of hydrogen gas reacts by the mass of 1 mol of hydrogen gas.
The change of enthalpy associated with the reaction of 1 mol of hydrogen gas can be determined by calculating the molar heat of reaction. Given that 2.16 g of H2 reacts with excess O2 and releases 258 kJ of heat, we can use this information to find the molar heat of reaction.
To calculate the molar heat of reaction, we first need to convert the mass of hydrogen gas to moles. The molar mass of hydrogen gas (H2) is 2 g/mol, so 2.16 g of H2 corresponds to (2.16 g / 2 g/mol) = 1.08 mol of H2.
Next, we divide the amount of heat released (258 kJ) by the number of moles of H2 (1.08 mol) to find the molar heat of reaction.
Molar heat of reaction = (258 kJ / 1.08 mol) ≈ 238.9 kJ/mol.
Rounding the result to the nearest whole number, the change of enthalpy associated with the reaction of 1 mol of hydrogen gas is approximately -239 kJ/mol. The negative sign indicates that the reaction is exothermic, releasing heat.
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Write the formula of the conjugate base of each acid: HI, HNO3, and CH3OH. Be sure to answer all parts. (Note: If a number has been placed as a subscript, the cursor needs to be returned to the main writing line before selecting the superscript.) Report Н SolL HI I Guided NO 3 HNO3 сH,о" CH3OH
The conjugate base of HI is I⁻, The conjugate base of HNO₃ is NO₃⁻, and CH₃OH is not an acid and does not have a conjugate base.
The conjugate base of an acid is formed when the acid donates a proton (H⁺). Let's determine the formula of the conjugate base for each acid;
HI (Hydroiodic acid)
Conjugate base: I⁻
The conjugate base of HI is the iodide ion, which is formed when HI donates a proton. The formula of the conjugate base is I⁻.
HNO₃ (Nitric acid)
Conjugate base: NO₃⁻
The conjugate base of HNO₃ is the nitrate ion, which is formed when HNO₃ donates a proton. The formula of the conjugate base is NO₃⁻.
CH₃OH (Methanol)
CH₃OH is not an acid. It is a neutral molecule and does not donate protons. Therefore, it does not have a conjugate base.
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why are we interested in the melting range of both crude and recrystallized solid?
The melting range of both crude and recrystallized solids is important because it provides information about the purity and identity of the substance and can indicate the presence of impurities or different forms of the compound.
The melting range is the temperature range over which a solid substance transitions from a solid to a liquid state. It is an essential property used in the characterization and identification of substances. For crude solids, which are typically impure and contain various impurities, the melting range can provide valuable information about the purity of the sample. Impurities present in the crude solid can lower the melting point and broaden the melting range. Therefore, a wide or lower-than-expected melting range for a crude solid indicates the presence of impurities.
Recrystallization is a purification technique used to obtain a more pure form of a substance. The melting range of a recrystallized solid is important because it serves as a criterion for assessing the success of the purification process. A narrower and higher melting range for a recrystallized solid indicates a higher degree of purity, as impurities are typically removed during the recrystallization process.
In summary, the melting range of both crude and recrystallized solids is significant as it provides information about the purity and identity of the substance. It allows for the detection of impurities in crude solids and serves as a measure of purification success in recrystallized solids.
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ka for hx is 7.5 x 10-10. what is the ph of a 0.15 m solution of nax?
pH of a 0.15 M solution of Na X is 5.70.
The given equation is :
HX + Na OH ⇌ Na X + H2O
The pH of a 0.15 M solution of Na X is required, so we first need to determine the concentration of HX. We may utilize the equation for the ionization of a weak acid to solve for the Ka of HX, as follows:
HX + H2O ⇌ H3O+ + X-Ka = [H3O+][X-] / [HX]Ka = [H3O+]2 / [HX]7.5 × 10-10 = [H3O+]2 / [HX]
We have the amount of HX in the solution (0.15 M), therefore:
[H3O+]2 = (7.5 × 10-10)(0.15)
Hence, [H3O+] = 2.02 × 10-6M
The pH and the hydrogen ion concentration in a given solution are related by the equation:
pH = - log [H^+]
Since the solution is aqueous, it must contain both hydrogen ions and hydroxide ions. The product of the hydrogen ion concentration and the hydroxide ion concentration in an aqueous solution is always constant, as given by the expression:
K_ w = [H^+][OH^-]
Where K_ w is the ion product constant of water, which has a value of 1.0 x 10^-14 at 25°C.
Next, we'll calculate the pH:
pH = -log[H3O+]pH = -log(2.02 × 10-6)pH = 5.70
Therefore, the pH of a 0.15 M solution of Na X is 5.70.
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Halfway to the equivalence point in a titration curve of a weak acid with a strong base, __________
a. nothing is happening yet.
b. pH = pKa of the weak acid.
c. pH = 3.5 exactly.
d. pH = pKa of the indicator.
e. the pH has not yet changed.
After considering all the given options we conclude that the satisfactory option for the given question is the pH has not yet changed, which is option E.
The pH of the solution progressively goes under an alteration when the titrant is added when titrating a weak acid with a strong base. The pH of the solution from the start is acidic because the weak acid dominates it before the equivalence point.
The weak acid is neutralized as the strong base is placed and interacts with it. The weak acid and strong base, however, have identical numbers of moles at the halfway point to the equivalence point, making a buffer system.
The weak acid's (pKa) dissociation constant is used to evaluate the solution's pH at the halfway point. The pH does not vary considerably and stays generally steady due to a buffer forms. Hence, the pH at the halfway point of the titration is the same as the pKa of the weak acid.
Finally, halfway to the equivalence point in a titration curve of a weak acid with a strong base, the pH has not yet changed.
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Calculate Δ∘ΔG∘ at 298 K for the reaction
CS2(l)+3O2(g)⟶CO2(g)+2SO2(g)CS2(l)+3O2(g)⟶CO2(g)+2SO2(g)
based on these reactions.
C(s)+O2(g)⟶CO2(g) Δ∘=−397.28 kJ/mol
S(s)+O2(g)⟶SO2(g) Δ∘=−300.19 kJ/mol
C(s)+2S(s)⟶CS2(l) Δ∘=+62.37 kJ/mol
Δ∘=
-1059.84kJ/mοl is Δ∘ at 298 K fοr the reactiοn
CS₂(l)+3O₂(g)⟶CO₂(g)+2SO₂(g)
Define enthalpyA thermοdynamic system's enthalpy, which is οne οf its prοperties, is calculated by adding the system's internal energy tο the prοduct οf its pressure and vοlume. It is a state functiοn that is frequently emplοyed in measurements οf chemical, biοlοgical, and physical systems at cοnstant pressure, which the sizable surrοunding envirοnment cοnveniently prοvides.
Because οf the internal energy's unknοwn, difficult-tο-access, οr irrelevant tο thermοdynamics cοmpοnents, the tοtal enthalpy οf a system cannοt be directly determined. Since it makes the descriptiοn οf energy transfer simpler, a change in enthalpy is typically the favοured fοrmulatiοn fοr measurements at cοnstant pressure.
CS₂(l)+3O₂(g)⟶CO₂(g)+2SO₂(g)
C(s)+O₂(g)⟶CO₂(g) Δ∘=−397.28 kJ/mοl
S(s)+O₂(g)⟶SO₂(g) Δ∘=−300.19 kJ/mοl (*2)
2S(s)+2O₂(g)⟶2SO₂(g) Δ∘=−600.19 kJ/mοl
C(s)+2S(s)⟶CS₂(l) Δ∘=+62.37 kJ/mοl
CS₂(l)⟶C(s)+2S(s) Δ∘=-62.37 kJ/mοl
Δ∘=−397.28−600.19-62.37
Δ∘= -1059.84kJ/mοl
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which of the following statements regarding orbitals is/are true?
~A 2p orbital is smaller than a 3p orbital.
~ A 1s orbital can be represented as a two-dimensional circle centered around the nucleus of an atom.
~There is no difference between the orbitals of the modern model of the atom and the orbits of the Bohr model of the atom.
~The p orbitals always come in sets of four.
~The d orbitals always have three lobes.
The statements: A 2p orbital is smaller than a 3p orbital and the p orbitals always come in sets of four are true. Rest of the statements are false.
A 2p orbital is smaller than a 3p orbital. This statement is true. The principal quantum number (n) indicates the energy level of the orbital, and as n increases, the size of the orbital increases. Therefore, a 2p orbital is smaller in size compared to a 3p orbital.
A 1s orbital can be represented as a two-dimensional circle centered around the nucleus of an atom. This statement is not true. The shape of the 1s orbital is spherically symmetric, and it cannot be accurately represented as a two-dimensional circle. The electron density of the 1s orbital is highest near the nucleus and gradually decreases as we move away from it.
There is no difference between the orbitals of the modern model of the atom and the orbits of the Bohr model of the atom. This statement is not true. The modern model of the atom, based on quantum mechanics, describes orbitals as probability distributions where electrons are likely to be found. In contrast, the Bohr model proposed specific, discrete orbits for electrons, which is now known to be an oversimplification.
The p orbitals always come in sets of four. This statement is true. In each energy level above the first (n > 1), there are three p orbitals: px, py, and pz. Each of these p orbitals has a different orientation in space but has the same energy.
The d orbitals always have three lobes. This statement is not true. The d orbitals have different shapes and can have various numbers of lobes. In fact, five out of the seven d orbitals have four lobes, while the other two have a different shape. The dxy, dxz, and dyz orbitals have two lobes, while the dz^2 and dx^2-y^2 orbitals have four lobes.
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Which of the following statements regarding triacylglycerols is not true? a. They are solid if they do not have alkene bonds. b. They are soluble in water. c. They are liquid if they have alkene bonds. d. They undergo alkaline hydrolysis to yield soaps.
e. Some can be hydrogenated.
The statement that is not true regarding triacylglycerols is b. They are soluble in water. Triacylglycerols are hydrophobic molecules and are insoluble in water.
Triacylglycerols, commonly known as fats or triglycerides, are composed of three fatty acid chains attached to a glycerol molecule. They serve as a major energy storage form in organisms. The physical properties of triacylglycerols vary depending on their composition.
Triacylglycerols are nonpolar molecules, meaning they have no charged or polar regions. Water, on the other hand, is a polar molecule. Due to the polarity difference, water molecules are unable to form stable interactions with the nonpolar triacylglycerol molecules. As a result, triacylglycerols are insoluble in water. Instead, they are soluble in nonpolar solvents like organic solvents (e.g., ether, chloroform) or lipids themselves. This hydrophobic nature of triacylglycerols is crucial for their role as energy storage molecules, allowing them to be stored in specialized adipose tissues in the body.
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calculate the mass in grams for 5.42 x 1022 molecules of propane, c3h8.
The mass of 5.42 x 10²² molecules of propane will be approximately 3.98 grams.
To calculate the mass in grams for a given number of molecules of propane (C₃H₈), you need to determine the molar mass of propane and then use it to convert the number of molecules to grams.
The molar mass of propane (C₃H₈) can be calculated by summing the atomic masses of its constituent elements;
C: 12.01 g/mol
H: 1.008 g/mol (there are 8 hydrogen atoms in propane)
Molar mass of propane (C₃H₈) = (3 × 12.01 g/mol) + (8 × 1.008 g/mol) = 44.11 g/mol
Now, to calculate the mass of 5.42 x 10²² molecules of propane:
1 mole of propane (C₃H₈) = 44.11 g
Therefore, 1 molecule of propane = 44.11 g / (6.022 x 10²³ molecules) (Avogadro's number)
To find the mass of 5.42 x 10²² molecules of propane, we can set up the following conversion;
5.42 x 10²² molecules of propane × (44.11 g / (6.022 x 10²³ molecules))
Simplifying the expression:
(5.42 x 10²²) × (44.11 g / 6.022 x 10²³) = 3.98 grams (rounded to two decimal places)
Therefore, the mass will be 3.98 grams.
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1.Which element is likely to have the ground-state electron configuration [Kr]5s14d10?
Au
In
Cd
Ag
Cu
The element likely to have the ground-state electron configuration [Kr]5s14d10 is Ag (Silver).
The electron configuration [Kr]5s14d10 corresponds to the filling of the 5s, 4d, and 4p orbitals in an atom. To determine the element with this electron configuration, we need to identify which element has the atomic number corresponding to the electron configuration.
The atomic number of Ag (Silver) is 47. When we fill the electrons based on the periodic table, the noble gas before element 47 is krypton (Kr), which has the electron configuration [Kr]4d105s2. The electron configuration [Kr]5s14d10 indicates that the 5s and 4d orbitals are fully filled, suggesting that the element is silver (Ag).
The other options, Au (Gold), In (Indium), Cd (Cadmium), and Cu (Copper), do not have the electron configuration [Kr]5s14d10. Au has the electron configuration [Xe]6s15d10, In has [Kr]5s24d105p1, Cd has [Kr]5s24d10, and Cu has [Ar]4s13d10.
Therefore, based on the electron configuration provided, the element likely to have the ground-state electron configuration [Kr]5s14d10 is Ag (Silver).
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Consider a sample of perfect gas (0.10 mol held inside a cylinder by a piston such that the volume is 1.25 dm3. The external pressure is constant at 1.00 bar and the cylinder rests in bath at constant temperature 300 K. The gas expands when the piston is released. Calculate i) The volume of the gas when the expansion is complete. ii) The work done when the gas expands. iii) The heat absorbed by the gas during expansion. iv) Total change in entropy.
i) The volume of the gas when the expansion is complete is approximately 2.49 dm³.
ii) The work done when the gas expands is -124 J.
iii) The heat absorbed by the gas during expansion is -124 J.
iv) The total change in entropy during the expansion is zero.
What is Ideal gas law?
The ideal gas law (PV = nRT) relates the macroscopic properties of ideal gases. An ideal gas is a gas in which the particles (a) do not attract or repel one another and (b) take up no space (have no volume).
To solve the given problem, we can use the ideal gas law and the first law of thermodynamics. Let's calculate each part step by step:
i) The volume of the gas when the expansion is complete:
Since the external pressure is constant, we can use the ideal gas law to find the final volume of the gas. The ideal gas law is given by:
PV = nRT
Where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature.
Given:
P = 1.00 bar = 1.00 × 10⁵ Pa (since 1 bar = 10⁵ Pa)
n = 0.10 mol
R = 8.314 J/(mol·K)
T = 300 K
Rearranging the ideal gas law equation to solve for V:
V = (nRT) / P
Plugging in the values:
V = (0.10 mol × 8.314 J/(mol·K) × 300 K) / (1.00 × 10⁵ Pa)
Calculating the volume:
V ≈ 2.49 dm³
Therefore, the volume of the gas when the expansion is complete is approximately 2.49 dm³.
ii) The work done when the gas expands:
The work done by the gas during expansion can be calculated using the equation:
Work = -Pext * ΔV
Where Pext is the external pressure and ΔV is the change in volume.
Given:
Pext = 1.00 bar = 1.00 × 10⁵ Pa
ΔV = Vfinal - Vinitial = 2.49 dm³ - 1.25 dm³ = 1.24 dm³
Converting ΔV to SI units:
ΔV = 1.24 dm³ = 1.24 × 10⁻³ m³
Calculating the work done:
Work = -(1.00 × 10⁵ Pa) * (1.24 × 10⁻³ m³) = -124 J
Therefore, the work done when the gas expands is -124 J (negative sign indicates work done on the gas).
iii) The heat absorbed by the gas during expansion:
According to the first law of thermodynamics, the change in internal energy (ΔU) of the gas is equal to the heat (Q) absorbed by the gas minus the work (W) done on the gas:
ΔU = Q - W
Since the expansion is taking place at constant temperature, the change in internal energy (ΔU) is zero (as internal energy depends only on temperature for an ideal gas).
Therefore, in this case, the heat absorbed by the gas (Q) is equal to the work done (W):
Q = W = -124 J
Thus, the heat absorbed by the gas during expansion is -124 J.
iv) The total change in entropy:
The total change in entropy (ΔS) can be calculated using the equation:
ΔS = ΔU / T
Since ΔU is zero (as explained above) and the temperature (T) is constant at 300 K, the total change in entropy is also zero.
Therefore, the total change in entropy during the expansion is zero.
In summary:
i) The volume of the gas when the expansion is complete is approximately 2.49 dm³.
ii) The work done when the gas expands is -124 J.
iii) The heat absorbed by the gas during expansion is -124 J.
iv) The total change in entropy during the expansion is zero.
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