the stability of hydrogen peroxide under normal storage conditions despite its negative ΔG° for decomposition can be attributed to the relatively high activation energy required for the reaction to occur.
How to solve the question?
The fact that the ΔG° for the decomposition of hydrogen peroxide (H2O2) is negative (-234 KJ/molrxn) indicates that the reaction is thermodynamically favorable, meaning that the products (water and oxygen gas) are more stable than the reactant (hydrogen peroxide). However, as mentioned in the question, hydrogen peroxide is typically stable for up to a year when stored in a dark bottle at 298K, which seems to contradict the thermodynamic prediction.
The best explanation for this observation is option D: the decomposition of hydrogen peroxide has a slow rate at 298 K because the activation energy is relatively high. Even though the reaction is thermodynamically favorable, it may not occur spontaneously at room temperature because the activation energy required to break the O-O bond in hydrogen peroxide is relatively high. This means that a significant amount of energy is needed to initiate the reaction and form the products, and at room temperature, the rate of the reaction is too slow for any significant decomposition to occur over a period of one year.
Additionally, the reaction is not reversible (option C) because the entropy of the system decreases due to the formation of liquid water from hydrogen peroxide and the release of oxygen gas. Option A is also incorrect because the decomposition of hydrogen peroxide does not require a catalyst to occur, although a catalyst can increase the rate of the reaction by lowering the activation energy.
In summary, the stability of hydrogen peroxide under normal storage conditions despite its negative ΔG° for decomposition can be attributed to the relatively high activation energy required for the reaction to occur.
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Solid ammonium hydroxide breaks down into gaseous ammonia, NH3, and liquid water.
Write a balanced equation for this reaction.
What is the reaction type
The balanced equation for the breakdown of solid ammonium hydroxide into gaseous ammonia and liquid water is:
[tex]NH_{4} OH[/tex](s) → [tex]NH_{3}[/tex] (g) + [tex]H_{2}O[/tex] (l)
This equation indicates that one molecule of solid ammonium hydroxide ([tex]NH_{4} OH[/tex]) decomposes to form one molecule of gaseous ammonia ([tex]NH_{3}[/tex]) and one molecule of liquid water ([tex]H_{2}O[/tex]).
The type of reaction that is occurring is a decomposition reaction. This is because one compound, ammonium hydroxide, is breaking down into two simpler substances, ammonia and water. Decomposition reactions can be induced by heat, light, or electricity and are a common type of chemical reaction in nature. In this case, the breakdown of ammonium hydroxide is likely to be endothermic since heat is required to break the bonds within the compound.
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please help this is dus today please help
A percentage expressing the variation between a calculated/measured value and the anticipated/real value is known as a "calculated percent error."
What does this mean?A positive numerical discrepancy implies that the assessed number exceeds what was expected, with negative values indicating the reverse.
When conducting an experiment, if an excessive percent error emerges it suggests potential errors or miscalculations in experimental design, data collection, or analysis.
This may mean unaccounted variables were present, and equipment/procedures require refinement. In opposition, lower percentages signal accuracy despite any limitations resulting from the human elements involved.
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Calculate the mass of butane needed to produce 50.0 g of carbon dioxide.
C4H10 + O2 --> CO2 + H2O
The mass must be balanced:
2C4H10 + 13O2 --> 8CO2 + 10H2O
The molar mass of butane is 12 × 4 + 10 = 58
The molar mass of carbon dioxide is 16 × 2 + 12 = 44
First, we calculate the moles of carbon dioxide produced
[tex]n_{CO2} = \frac{50,0 g}{44 g/mol} = 1,14 mol[/tex]
If 2 moles of butane are needed for produce 8 moles of CO2 then x moles of butane are needed to produce 1,14 moles of CO2, therefore
[tex]\frac{2}{8} = \frac{x}{1,14} \\ \\ x = \frac{1,14}{4} = 0,285 mol[/tex]
Then the moles can be multiplied by the molar mass of butane in order to get the total mass of butane burned.
[tex]m_{C4H10} = 0,285 mol × 58 g/mol = 1,65 g[/tex]
Macmillan Learning
A 346.9 mL sample of carbon dioxide was heated to 373 K. If the volume of the carbon dioxide sample at 373 K is 596.2 mL,
what was its temperature at 346.9 mL?
T=. K
Answer:
Explanation:
Use the Equation: [tex]\frac{V1}{T1}=\frac{V2}{T1} \\[/tex]
V1 = 346.9 mL
T1 = ? K
V2 = 596.2 mL
T2 = 373 L
This assumption can only be made when pressure is held constant.
[tex]\frac{346.9}{V1}=\frac{596.2}{373}, solve for V1\\ V1 = 217.0 K[/tex]
Is my option correct?
Answer:
No, See explanation. Should be A.
Explanation:
No, the correct answer appears to be A. Particle B is past the required potential energy to react. This means that this particle has enough energy to react and does not require to be heated or energy imputed further.
The alcoholic, blue solution from Part I of your experiment is commonly used in weather-forecasting devices found in coastal areas of the USA. Based on your observations in the lab explain how this reaction can indicate coming rain
Answer:
The reaction referred to in this question is likely the reaction between hydrated copper(II) sulfate and anhydrous copper(II) sulfate, where the former is blue and the latter is white.
When the blue solution of hydrated copper(II) sulfate is exposed to moist air, it slowly turns white as water is absorbed, forming anhydrous copper(II) sulfate. This reaction is exothermic, meaning it releases heat, and is reversible. The reverse reaction occurs when anhydrous copper(II) sulfate is exposed to water vapor in the air, forming hydrated copper(II) sulfate and releasing heat.
In coastal areas, the humidity in the air tends to increase before a storm, which can trigger the reverse reaction between anhydrous copper(II) sulfate and water vapor. This releases heat, causing the weather-forecasting device to warm up, indicating that rain may be on the way.
Therefore, the observation of the blue solution turning white in the lab, which indicates the reversible reaction between hydrated copper(II) sulfate and anhydrous copper(II) sulfate, can indirectly indicate the presence of moisture in the air and the possibility of rain, similar to the process in weather-forecasting devices.
Question 22 of 25
Which of the following is a carboxylic acid?
O
НИИ
II
A. н-с-с-с-с
ИНИ
НИИ
в. н-с-с-с-с
III о-н
ИНН
ИНИ
I II
с. н-с-с-с-
Н
ННИ
ТТІ
O D. H-C-C-C-C
JIT
ИНН
OCH,
CH₂
The answer is B since the carboxylic acid group is COOH
A fjord is _____ .
a high mountain
a steep-sided glacial valley
an oceanic mountain range
a glacial plain
Answer:
a steep-sided glacial valley
Explanation:
A fjord is a long, narrow inlet with steep sides or cliffs, created by a glacier. It is a long, deep, narrow body of water that reaches far inland. Fjords are found mainly in Norway, Chile, New Zealand, Canada, Greenland, and Alaska. They are formed when a glacier cuts a U-shaped valley by ice segregation and abrasion of the surrounding bedrock. According to the standard model, glaciers formed in pre-glacial valleys with a gently sloping valley floor. The work of the glacier then left an over deepened U-shaped valley that ends abruptly at a valley or trough end. Such valleys are fjords when flooded by the ocean. Thresholds above sea level create freshwater lakes.
PLS HELP!!!!!
Convert the following measurements. Show all work, including units that cancel.
9.3 mol SO3 -> liters
Answer: 9.3 mol of SO3 at STP occupies 20.2 liters.
Explanation: To convert from moles of a gas to liters, we need to use the ideal gas law:
PV = nRT
where:
P = pressure in atm
V = volume in liters
n = number of moles
R = gas constant (0.08206 L·atm/mol·K)
T = temperature in Kelvin
We can rearrange this equation to solve for V:
V = (nRT)/P
First, let's calculate the volume of 9.3 mol of an ideal gas at standard temperature and pressure (STP). STP is defined as 0°C (273.15 K) and 1 atm.
V = (9.3 mol * 0.08206 L·atm/mol·K * 273.15 K) / 1 atm
V = 20.2 L
Therefore, 9.3 mol of SO3 at STP occupies 20.2 liters.
Note that this assumes SO3 is an ideal gas, which may not be the case in reality.
DNA is the building block of life, but were you surprised to find out that only 4 base pairs make up every living thing we know of on this planet? How is DNA held together in the double helix? Imagine you were a scientist that discovered one of these important findings out about DNA. Write me a short story that shows your excitement about discovering what life is made up of.
3. A solution of hydrochloric acid is made by dissolving hydrogen chloride gas in 100.0ml water. This solution neutralizes a 15ml sample of 0.10 mol/L sodium carbonate solution. a. What mass of hydrogen chloride gas was dissolved in 100.0ml of water? b. What volume of hydrogen chloride was this?
Okay, here are the steps to solve this problem:
a) To neutralize 15ml of 0.10 mol/L sodium carbonate solution, the hydrochloric acid solution must contain 0.015 moles of HCl.
Since the HCl solution is made by dissolving HCl gas in 100ml water, we can calculate the moles of HCl gas dissolved in 100ml:
0.015 moles HCl / 15ml sodium carbonate solution = X moles HCl gas / 100ml HCl solution
X = 0.015 * (100/15) = 0.01 moles HCl gas
b) Molar volume of HCl gas at STP is 24.45 L/mol.
So the volume of 0.01 moles HCl gas is: 0.01 moles * 24.45 L/mol = 0.2445 L
Since the solution is made with this gas in 100ml water, the volume of HCl gas dissolved in 100ml water is 0.2445 L.
So the final answers are:
a) 0.01 moles of HCl gas
b) 0.2445 L of HCl gas
Please let me know if you have any other questions!
For which of the following reactions does ΔH
o
rxn
= ΔH
o
f
?
(a) H2(g) + S(rhombic) → H2S(g)
(b) C(diamond) + O2(g) → CO2(g)
(c) H2(g) + CuO(s) → H2O(l) + Cu(s)
(d) O(g) + O2(g) → O3(g)
ΔH° = ΔHf° is true for two reactions which are ,
H₂(g) + S(rhombic) → H₂S(g)
C(diamond) + O₂(g) → CO₂(g)
Hence, option a and b are correct.
∆Hf is the enthalpy of formation, is the enthalpy when product is made from its constituent elements. Generally the enthalpy of formation is described as the standard reaction enthalpy for the formation of the compound from its elements (which may include atoms or molecules) in their most stable reference states at the chosen temperature (298.15K) and at 1bar pressure.
In a part, H₂S is formed by H₂ and S means it's constituent elements.
So, a is correct.
In b also, CO₂ is formed by C and O₂, so b is also correct. Hence, option a and b are correct.
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A 0.431-g sample of an unknown monoprotic acid was titrated with 0.108 M KOH and the resulting titration curve is shown here.
1. Determine the molar mass of the acid.
2. Determine the pKa of the acid.
1) The molar mass of the acid of the titration curve is 166 g/mol
2) The pKa of the acid of the titration curve is 4.97.
1) The molar mass of the acid can be determined from the equivalence point of the titration curve
Mass of acid sample = 0.431 g
Volume of KOH solution at equivalence point = 24.0 mL = 0.0240 L
Molarity of KOH solution = 0.108 M
Number of moles of KOH added at equivalence point = Molarity x Volume
= 0.108 M x 0.0240 L
= 0.00259 moles
Number of moles of acid = Number of moles of KOH added
= 0.00259 moles
Molar mass of acid = Mass of acid sample ÷ Number of moles of acid
= 0.431 g ÷ 0.00259 moles
= 166 g/mol
2) The pKa of the acid can be determined from the half-equivalence point of the titration curve.
Volume of KOH solution at half-equivalence point = 11.5 mL = 0.0115 L
Number of moles of KOH added at half-equivalence point = Molarity x Volume
= 0.108 M x 0.0115 L
= 0.00124 moles
Concentration of acid at half-equivalence point = Number of moles of acid remaining ÷ Volume of acid
= (0.431 g - (0.00124 moles x 56.1 g/mol)) ÷ 0.025 L
= 0.017 M
Concentration of conjugate base at half-equivalence point = Number of moles of KOH added ÷ Volume of KOH
= 0.00124 moles ÷ 0.0115 L
= 0.108 M
pKa = pH + log([conjugate base] ÷ [acid])
= 7.08 + log(0.108 ÷ 0.017)
= 4.97
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Explain to me please????
Answer:Non polar.
Explanation:because water is polar because of its shape
A 0.675 mole sample of oxygen gas has a pressure of 2.50 atm at 50. °C. What volume of gas is present
in the sample? Show the rearranged ideal gas law solving for volume. Cancel units in work.
Considering the ideal gas law, the volume of gas present in the sample is 7.15122 L.
Definition of Ideal Gas LawIdeal gases are a simplification of real gases that is done to study them more easily. It is considered to be formed by point particles, do not interact with each other and move randomly. It is also considered that the molecules of an ideal gas, in themselves, do not occupy any volume.
An ideal gas is characterized by three state variables: absolute pressure (P), volume (V), and absolute temperature (T). The relationship between them constitutes the ideal gas law, an equation that relates the three variables if the amount of substance, number of moles n, remains constant and where R is the molar gas constant:
P×V = n×R×T
Volume of gas in this caseIn this case, you know:
P= 2.50 atmV= ?n= 0.675 molesR= 0.082 (atmL)/(molK)T= 50 C= 323 K (being 0 C= 273 K)Replacing in the ideal gas law:
2.50 atm×V = 0.675 moles×0.082 (atmL)/(molK)× 323 K
Solving:
V= (0.675 moles×0.082 (atmL)/(molK)× 323 K)÷ 2.50 atm
V= 7.15122 L
Finally, the volume of gas is 7.15122 L.
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Which is expected to have the largest dispersion forces?
Question 13 options:
N2
C2H6
CO2
C8H18
The molecule with the highest molecular weight and the largest number of electrons, C₈H₁₈, is expected to have the largest dispersion forces, option (d) is correct.
The dispersion forces, also known as London dispersion forces, are a type of intermolecular force that arises due to the temporary dipoles that occur in non-polar molecules. The molecule C₈H₁₈ with the largest number of electrons and the highest molecular weight is expected to have the largest dispersion forces.
This molecule has a larger number of electrons and a larger surface area for intermolecular interactions, which results in stronger dispersion forces compared to the other molecules, option (d) is correct.
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The complete question is:
Which is expected to have the largest dispersion forces?
a. N₂
b. C₂H₆
c. CO₂
d. C₈H₁₈
AP Environmental Science: According to the diagram, crude oil can be heated and separated into various components. In one barrel of oil, 22 percent is refined into gasoline and 38 percent into diesel fuel.
When the price of a barrel of oil increases, which of the following statements is the most accurate prediction of what will happen?
- The price of gasoline will increase in direct proportion to the increase in a barrel of oil.
- Bitumen for roads and roofing will be affected in supply but not in price.
- Diesel fuels will not be affected in price and can be manufactured from ethanol.
- The price of jet fuel will follow the inverse relationship and increase quickly in cost.
Okay, here are the key points to consider:
- Crude oil is separated into various components like gasoline, diesel fuel, jet fuel, bitumen, etc.
- A barrel of oil contains 22% gasoline and 38% diesel fuel. So these components make up a major portion of the oil.
- When the price of a barrel of oil increases, the costs to produce these components like gasoline and diesel also go up.
- So the prices of gasoline, diesel fuel and other components are directly linked to the price of crude oil. They will likely increase proportionally if oil price rises.
- Bitumen may be affected in supply but its price could still adjust based on supply and demand. It's linked to oil price indirectly.
- Diesel fuel price will also likely rise with oil price increase. It cannot be produced just from ethanol. It requires crude oil.
- Jet fuel price will also follow the increase in oil price. It's not inverse.
So among the options, the choice that is most accurate is:
The price of gasoline will increase in direct proportion to the increase in a barrel of oil.
The other options are not fully supported. Diesel and jet fuel prices will rise, bitumen may see some supply impact but prices will adjust, and prices are directly linked to oil prices, not inversely.
Let me know if you need more explanation.
2C +2H yield C2H4 Delta H=+52.4 kj/mol
What is the kj of energy absorbed for every mole of carbon reacted
The kJ of the energy absorbed for the every mole of the carbon reacted is 104.8 kJ.
The chemical equation is as :
2C + 2H ---> C₂H₄ , ΔH = + 52.4 kJ/mol
The ΔH is the enthalpy change that is determined by the subtracting the energy of the reactants to the products.
The ΔH = energy of the products - energy of the reactants
The expression for the energy is as :
q = n ΔH
Where,
n = number of the moles
ΔH = enthalpy change
The kJ of the energy absorbed for the every mole of the carbon reacted :
q = 2 mol × 52.4 kJ/mol
q = 104.8 kJ
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Objective Questions I (Only one correct option) 1. Atom X occupies the fcc lattice sites as well as alternate tetrahedral voids of the same lattice. The packing efficiency (in %) of the resultant solid is closest to (2022 Adv.) (a) 25 (b) 35 (c) 55 (d) 75 a hcp
The packing efficiency (in %) of the resultant solid is (d) 75.
What is packing efficiency of a crystal lattice?Packing efficiency of a crystal lattice refers to the percentage of space in a given volume that is occupied by atoms, ions, or molecules in the lattice.
The closest packing efficiency of a crystal lattice is given by the formula:
packing efficiency = (number of atoms in the unit cell x volume of each atom) / volume of the unit cell
For an fcc lattice, the number of atoms in the unit cell is 4, and for an alternate tetrahedral void, the number of atoms is 2. Therefore, the total number of atoms in the unit cell is 4 + 2 = 6.
The packing efficiency of fcc is 74%, which means the volume occupied by the atoms is 74% of the total volume of the unit cell. When the alternate tetrahedral voids are filled with atoms, the total number of atoms increases, and the volume occupied by the atoms also increases. Hence, the packing efficiency will be greater than 74%.
The closest option to the calculated value is (d) 75. Therefore, the answer is (d) 75.
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4. The complete chemical equations for reactions a-e on the Experimental Page are
listed below. Balance each equation by placing the proper coefficient in front c
each chemical formula so that each side of the equation has the same number
atoms of each element.
NaOH +
HCI →>>
NaCl +
HOH
What would the expected temperature change be (in °C) if a 0.5 gram sample of water released 0.0501 kJ of heat energy? The specific heat of liquid water is 4.184 J/g-°C.
Using the equation q = mcT, where q is the amount of heat energy released (0.0501 kJ), m is the sample's mass (0.5 g), c is the specific heat of liquid water (4.184 J/g-°C), and T is the temperature change, one can determine the anticipated temperature change for a 0.5 gramme sample of water that releases 0.0501 kJ of heat energy.
T = q / (mc) is the result of rearranging the equation. We calculate T = 0.0501 kJ / (0.5 g * 4.184 J/g-°C) = 0.6022 °C by plugging in the given variables.
As a result, a 0.5 gramme sample of water that releases 0.0501 kJ of heat energy should have an estimated temperature change of 0.6022 °C.
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What is the calibration of this graduated cylinder? calibration
A. 5 mL
B. 2 mL
C. 1 mL
D. 10 mL
The answer is 1ml. The answer is 1ml because of calibration of this graduated cylinder
Answer:
1 mL
Explanation:
According to your definition, it is the difference between marked spaces divided by the # of spaces between marked values.
Difference between 2 marked values: 5 mL
# Of Spaces between marked values: 5
Calibration: 5 mL / 5 mL = 1 mL
NH4NO3 is ammonium nitrate is used for supplies ammonium and nitrate ions.
a. Calculate the percentage nitrogen, hydrogen and oxygen by mass in this fertilizer.
b. Calculate the mass of nitrogen in 500kg of ammonium nitrate
Relative atomic masses: H = 1; N = 14 ; O= 16
Among the elements of the main group, the first ionization energy increases
from left to right across a period.
from right to left across a period.
when the atomic radius increases.
down a group
The first ionisation energy increases over time from left to right among the major group of elements. answer is option (a).
What is Ioniztion?When an element loses its valence electron, its oxidation number increases (a process known as oxidation), and this energy loss is known as ionisation (Ei).
Earth alkaline metals, which are located immediately next to alkaline metals, have higher ionisation energies than alkaline metals because they have two valence electrons, while alkaline metals, which are located far left in the main group, have the lowest ionisation energies and are easiest to remove.
Because they contain a large number of valence electrons, nonmetals are far to the right in the main group and have the highest ionisation energy.
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The complete question is,
Among the elements of the main group, the first ionization energy increases
a. from left to right across a period.
b. from right to left across a period.
c. when the atomic radius increases.
d. down a group.
The combustion of FeS forms Fe2O3 and SO2. The combustion of SO2 forms SO3. The SO3 can be treated with water to form sulfuric acid, H2SO+. How many grams of H2SO4 can be produced from 422 grams of iron ore containing 75.0% FeS.
Therefore, approximately 235.6 grams of Sulfuric Acid can be produced from 422 grams of iron ore containing 75.0% Iron(II) sulfide.
What function does Sulfuric Acid provide in iron estimation?
During such a titration, sulfuric acid is added to maintain the medium's acidity and meet the stoichiometric needs of the redox reaction. Additionally, extra amounts are injected to supply the protons (H+) needed for the redox reaction.
We can begin by figuring out how much Iron(II) sulfide there is in the 422 grammes of iron ore:
mass of FeS = 422 g x 0.75 = 316.5 g
We can see from the equation that everything balances out that 1 mol of FeS combines with 1.5 mol of sulfur dioxide to create 1 mol of Sulfuric Acid. Therefore, we must first determine the amount of Iron(II) sulfide in moles:
moles of Iron(II) sulfide = mass of Iron(II) sulfide / molar mass of Iron(II) sulfide
moles of Iron(II) sulfide = 316.5 g / 87.91 g/mol
moles of Iron(II) sulfide = 3.597 mol
Next, we can determine the quantity of moles of Sulfuric Acid generated using the stoichiometric ratios from the balanced equations:
1 mol sulfur dioxide : 1.5 mol sulfur dioxide : 1 mol Sulfuric Acid
3.597 mol : 5.3955 mol : x mol Sulfuric Acid
x mol Sulfuric Acid = (3.597 mol Iron(II) sulfide) x (1 mol Sulfuric Acid / 1 mol FeS) x (1.5 mol sulfur dioxide / 1 mol FeS) x (1 mol Sulfuric Acid / 1.5 mol SO2)
x mol H2SO4 = 2.398 mol
Finally, we can determine the mass of created Sulfuric Acid:
mass of Sulfuric Acid = moles of Sulfuric Acid x molar mass of Sulfuric Acid
mass of Sulfuric Acid = 2.398 mol x 98.079 g/mol
mass of Sulfuric Acid = 235.6 g.
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A sample of sodium azide (NaN3), a compound used in automobile air bags, was thermally decomposed, and 15.3 mL nitrogen gas was collected over water at 25°C and 755 torr. Given the vapour pressure of water at 25°C is 23.6 torr, how many grams of nitrogen were collected?
A sample of sodium azide (NaN3), a compound used in automobile air bags, was thermally decomposed, and 15.3 mL nitrogen gas was collected over water at 25°C and 755 torr. 131.1g is the mass of nitrogen.
In physics, mass is a quantitative measurement of inertia, a basic characteristic of all matter. It essentially refers to a body of matter's resistance to changing its speed or location in response to the application for a force.
The change caused by a force being applied is smaller the more mass a body has. The kilogramme, which is defined approximately equal to 6.62607015 1034 joule second in terms of Planck's constant, is the unit of mass within the Internacional System of Units (SI).
P×V = n×R×T
755×15.3 = n×0.0821×300
11551.5=n×24.63
n= 46.9
mass = 46.9×28=131.1g
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50 points, and I’ll mark as brainliest!!!
Problem 1. Sea water contains dissolved salts at a total ionic concentration of about 1.13 mol×L–1. What pressure must be applied to prevent osmotic flow of pure water into sea water through a membrane permeable only to water molecules (at 25oC)?
Problem 2. What is the osmotic pressure of a solution prepared by adding 6.65 g of glucose to enough water to make 350 mL of solution at 35°C?
Problem 3. What is the osmotic pressure of a solution prepared by adding 9.0 g of glucose to enough water to make 450 mL of solution at 35°C?
Problem 4. What is the osmotic pressure of a solution prepared by adding 11.0 g of propanol to enough water to make 850 mL of solution at 25°C?
Problem 5. What is the osmotic pressure of a solution prepared by adding 65 g of glucose to enough water to make 35000 mL of solution at 15°C?
Problem 1:
The osmotic pressure (π) can be calculated using the van 't Hoff equation: π = iMRT, where i is the van 't Hoff factor (1 for water), M is the molar concentration, R is the gas constant, and T is the temperature in Kelvin.
In this case, the molar concentration is 1.13 mol/L, and the temperature is 25°C = 298 K. So,
π = iMRT = (1)(1.13 mol/L)(0.08206 L·atm·K⁻¹·mol⁻¹)(298 K)
π = 29.8 atm
Therefore, a pressure of 29.8 atm must be applied to prevent osmotic flow of pure water into sea water through a membrane permeable only to water molecules at 25°C.
Problem 2:
The osmotic pressure of a solution can be calculated using the van 't Hoff equation: π = iMRT, where i is the van 't Hoff factor, M is the molar concentration, R is the gas constant, and T is the temperature in Kelvin.
First, we need to find the molar concentration of glucose in the solution. The molecular weight of glucose is 180.16 g/mol. So,
Molar concentration = (mass/volume) / (molecular weight)
Molar concentration = (6.65 g/0.35 L) / 180.16 g/mol
Molar concentration = 0.104 mol/L
Now, we can calculate the osmotic pressure:
π = iMRT = (1)(0.104 mol/L)(0.08206 L·atm·K⁻¹·mol⁻¹)(308 K)
π = 2.44 atm
Therefore, the osmotic pressure of the solution prepared by adding 6.65 g of glucose to enough water to make 350 mL of solution at 35°C is 2.44 atm.
Problem 3:
Using the same process as in Problem 2, we can find the molar concentration of glucose in the solution:
Molar concentration = (mass/volume) / (molecular weight)
Molar concentration = (9.0 g/0.45 L) / 180.16 g/mol
Molar concentration = 0.44 mol/L
Now, we can calculate the osmotic pressure:
π = iMRT = (1)(0.44 mol/L)(0.08206 L·atm·K⁻¹·mol⁻¹)(308 K)
π = 10.2 atm
Therefore, the osmotic pressure of the solution prepared by adding 9.0 g of glucose to enough water to make 450 mL of solution at 35°C is 10.2 atm.
Problem 4:
Propanol (C₃H₇OH) is a non-electrolyte, so its van 't Hoff factor is 1.
First, we need to find the molar concentration of propanol in the solution. The molecular weight of propanol is 60.10 g/mol. So,
Molar concentration = (mass/volume) / (molecular weight)
Molar concentration = (11.0 g/0.85 L) / 60.10 g/mol
Molar concentration = 0.178 mol/L
Now, we can calculate the osmotic pressure:
π = iMRT = (1)(0.178 mol/L)(0.08206 L·atm·K⁻¹·mol⁻¹(298 K)
π = 3.67 atm
Therefore, the osmotic pressure of the solution prepared by adding 11.0 g of propanol to enough water to make 850 mL of solution at 25°C is 3.67 atm.
Problem 5:
Using the same process as in Problem 2 and Problem 3, we can find the molar concentration of glucose in the solution:
Molar concentration = (mass/volume) / (molecular weight)
Molar concentration = (65 g/35,000 mL) / 180.16 g/mol
Molar concentration = 0.00177 mol/L
Now, we can calculate the osmotic pressure:
π = iMRT = (1)(0.00177 mol/L)(0.08206 L·atm·K⁻¹·mol⁻¹)(288 K)
π = 0.0398 atm
Therefore, the osmotic pressure of the solution prepared by adding 65 g of glucose to enough water to make 35,000 mL of solution at 15°C is 0.0398 atm.
What is the energy change for the following equation?
Answer:
1) -572 kJ/mol
2) -2220.7 kJ/mol
Explanation:
Multiply the bond enthalpies to take into account the amount of moles of each compound in the reaction. Then, to get the total change in energy/enthalpy in the reaction, subtract the reactant energy from the product energy.
1) 2(-286) = -572 kJ/mol
2) 4(-286) + -393.5(3) - -103.8 = -2220.7 kJ/mol
How many chloride ions are in 15.0 mL of a 2.5 molar solution of magnesium chloride? (MgCl2)
In 15.0 mL of a 2.5 molar magnesium chloride solution, there are approximately 4.51 × 10^{22} chloride ions.
How many chloride ions are there in MgCl_2?An inorganic compound composed of one magnesium ion and two chloride ions.
We must first determine the number of moles of MgCl_2 in the solution,
moles of solute = concentration × volume (in liters)
Converting the solution's volume from milliliters to liters,
15.0 mL = 15.0 × 10^{-3} L
moles of MgCl_2 = 2.5 mol/L × 15.0 × 10^{-3} L = 0.0375 moles
The solution contains the following number of chloride ions:
number of Cl^{-} ions = 2 × moles of MgCl_2
Substitute the value of moles of MgCl_2,
number of Cl^{-} ions = 2 × 0.0375 moles = 0.075 moles
by using Avogadro's number:
number of Cl^{-} ions = 0.075 moles × 6.02 × 10^{23} ions/mol ≈ 4.51 × 10^{22} ions
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What quantity of heat (in J) would be required to convert 0.27 mol of a pure substance from a liquid at 50 °C to a gas at 113.0 °C?.
Cliquid = 1.45 J/mol C
Cgas = 0.65 J/mol *C
Tboiling = 88.5 °C
AHvaporization = 1.23 kJ/mol
Give your answer in Joules
Explanation:
First you have to heat the liquid from 50 to 88.5 C to get it boiling...
then you need to boil it all to a gas....the you have to heat it to 113 C
.27 mole *
( (88.5 -50 C)*1.45 J / (mole-C) <====heating the liquid
+ 1230 J / mole <====boiling to a gas
+ (113 - 88.5 C) * .65 J/(mole C) <=====heating the gas
= 351 .5 J <=====result